Green adsorbents for pharmaceutics removal from urine: Analysis of isotherms, kinetics, adsorption interactions, cost estimation, and environmental impact

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dc.contributor.affiliationParedes-Laverde M., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia
dc.contributor.affiliationCárdenas-Jiménez J.A., Departamento de Química, CUCEI, Universidad de Guadalajara, Marcelino García Barragán 1421, Jalisco, Guadalajara, C.P. 44430, Mexico, Grupo de Materiales con Impacto, Mat&mpac, Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, Colombia
dc.contributor.affiliationPorras J., Grupo de Investigaciones Biomédicas Uniremington, Facultad de Ciencias de la Salud, Corporación Universitaria Remington (Uniremington), Calle 51 No. 51-27, Medellín, Colombia
dc.contributor.affiliationAcelas N., Grupo de Materiales con Impacto, Mat&mpac, Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, Colombia
dc.contributor.affiliationTorres-Palma R.A., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia
dc.contributor.authorParedes-Laverde M.
dc.contributor.authorCárdenas-Jiménez J.A.
dc.contributor.authorPorras J.
dc.contributor.authorAcelas N.
dc.contributor.authorTorres-Palma R.A.
dc.date.accessioned2024-12-27T20:51:44Z
dc.date.available2024-12-27T20:51:44Z
dc.date.issued2024
dc.descriptionHusks of rice (RH), coffee (CH), and cholupa (CLH) were used to produce natural adsorbents. The natural adsorbents were used to remove pharmaceuticals such as diclofenac, ciprofloxacin, and acetaminophen in a mixture of distilled water. However, CH stood out for its efficiency in removing ciprofloxacin (74%) due to the higher concentration of acidic groups, as indicated by the Boehm method. In addition, CH removed 86% of ciprofloxacin individually. Therefore, CH was selected and used to remove other fluoroquinolones, such as levofloxacin and Norfloxacin. Although electrostatic interactions favored removals, better removal was observed for ciprofloxacin due to its smaller molecular volume. Then, ciprofloxacin was selected, and the effect of pH, matrix, and adsorbent doses were evaluated. In this way, using a pH of 6.2 in urine with a dose of 1.5 g L−1, it is possible to adsorb CIP concentrations in the range (0.0050–0.42 mmol L−1). Subsequently, the high R2 values and low percentages of APE and Δq indicated better fits for pseudo-second-order kinetics, suggesting a two-stage adsorption. At the same time, the Langmuir isotherm recommends a monolayer adsorption with a Qm of 25.2 mg g−1. In addition, a cost of 0.373 USD/g CIP was estimated for the process, where the material can be reused up to 4 times with a CIP removal in the urine of 51%. Consequently, thermodynamics analysis showed an exothermic and spontaneous process with high disorder. Furthermore, changes in FTIR analysis after adsorption suggest that CH in removing CIP in urine involves electrostatic attractions, hydrogen bonds and π-π interactions. In addition, the life cycle analysis presents, for the 11 categories evaluated, a lower environmental impact of the CIP removal in urine with CH than for the preparation of adsorbent, confirming that the adsorption process is more environmentally friendly than materials synthesis or other alternatives of treatments. Furthermore, future directions of the study based on real applications were proposed. © 2024 Elsevier Ltd
dc.identifier.doi10.1016/j.jenvman.2024.122162
dc.identifier.instnameinstname:Universidad de Medellínspa
dc.identifier.issn3014797
dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellínspa
dc.identifier.repourlrepourl:https://repository.udem.edu.co/
dc.identifier.urihttp://hdl.handle.net/11407/8683
dc.language.isoeng
dc.publisher.facultyFacultad de Ciencias Básicasspa
dc.relation.citationvolume368
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85200829077&doi=10.1016%2fj.jenvman.2024.122162&partnerID=40&md5=3267a097e6c63457e19a52b258a56ea7
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dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.sourceJournal of Environmental Management
dc.sourceJ. Environ. Manage.
dc.sourceScopus
dc.subjectCarbon footprinteng
dc.subjectEco-adsorbenteng
dc.subjectFluoroquinoloneseng
dc.subjectLife cycle analysiseng
dc.subjectWaste recoveryeng
dc.subjectAdsorptioneng
dc.subjectAntibioticseng
dc.subjectCost estimatingeng
dc.subjectElectrostaticseng
dc.subjectEnvironmental impacteng
dc.subjectHydrogen bondseng
dc.subjectIsothermseng
dc.subjectLife cycleeng
dc.subjectMonolayerseng
dc.subjectadsorbenteng
dc.subjectciprofloxacineng
dc.subjectdiclofenaceng
dc.subjectlevofloxacineng
dc.subjectnorfloxacineng
dc.subjectparacetamoleng
dc.subjectquinolone derivativeeng
dc.subjectAdsorption interactionseng
dc.subjectCost estimationseng
dc.subjectDiclofenaceng
dc.subjectEco-adsorbenteng
dc.subjectFluoroquinoloneseng
dc.subjectInteraction costeng
dc.subjectLife cycle analysiseng
dc.subjectNatural adsorbentseng
dc.subjectUrine analysiseng
dc.subjectWaste recoverieseng
dc.subjectadsorptioneng
dc.subjectArticleeng
dc.subjectcarbon footprinteng
dc.subjectcoffeeeng
dc.subjectenvironmental impacteng
dc.subjectFourier transform infrared spectroscopyeng
dc.subjecthydrogen bondeng
dc.subjectisothermeng
dc.subjectkineticseng
dc.subjectlife cycleeng
dc.subjectnonhumaneng
dc.subjectpHeng
dc.subjectpharmaceuticseng
dc.subjectriceeng
dc.subjectstatic electricityeng
dc.subjectsynthesiseng
dc.subjectthermodynamicseng
dc.subjecturinalysiseng
dc.subjecturineeng
dc.subjectCarbon footprinteng
dc.titleGreen adsorbents for pharmaceutics removal from urine: Analysis of isotherms, kinetics, adsorption interactions, cost estimation, and environmental impacteng
dc.typeArticle
dc.type.localArtículo de revistaspa
dc.type.versioninfo:eu-repo/semantics/publishedVersion

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