Challenges and potential future trends on high entropy alloy for solid hydrogen storage: Systematic review

dc.contributor.affiliationLenis J.A., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationArias Velandia J., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationAguirre Ocampo R., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationZuleta Gil A.A., Grupo de Investigación de Estudios en Diseño - GED, Facultad de Diseño Industrial, Universidad Pontificia Bolivariana, Sede Medellín, Circular 1 No 70 – 01, Medellín, Colombia
dc.contributor.affiliationBello S., Grupo de Investigación Materiales con Impacto – MAT&MPAC, Facultad de Ingenierías, Universidad de Medellín UdeM, Carrera 87 No 30 – 65, Medellín, Colombia
dc.contributor.affiliationCorrea E., Grupo de Investigación Materiales con Impacto – MAT&MPAC, Facultad de Ingenierías, Universidad de Medellín UdeM, Carrera 87 No 30 – 65, Medellín, Colombia
dc.contributor.affiliationArrieta C., Grupo de Investigación en Ingeniería en Energía – GRINEN, Facultad de Ingenierías, Universidad de Medellín UdeM, Carrera 87 No 30 – 65, Medellín, Colombia
dc.contributor.affiliationBolívar F.J., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationEcheverría Echeverría F., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.authorLenis J.A.
dc.contributor.authorArias Velandia J.
dc.contributor.authorAguirre Ocampo R.
dc.contributor.authorZuleta Gil A.A.
dc.contributor.authorBello S.
dc.contributor.authorCorrea E.
dc.contributor.authorArrieta C.
dc.contributor.authorBolívar F.J.
dc.contributor.authorEcheverría Echeverría F.
dc.date.accessioned2025-09-08T14:23:26Z
dc.date.available2025-09-08T14:23:26Z
dc.date.issued2025
dc.descriptionThis work consists of a systematic review showing recent progress and trends in the development of high entropy alloys (HEA) for solid-state hydrogen storage. The information was compiled from academic papers from the following databases: Google Scholar, ScienceDirect, Springer, SCOPUS, American Chemical Society, MDPI; as well as the patent banks United States Patent and Trademark Office, Google Patent and lens.org. This article discusses key aspects such as HEA design (elements used, thermodynamic and geometric characteristics, thermodynamic simulations and synthesis methods); HEA evaluation focusing on crystallinity, thermal behavior and hydrogen storage; HEA-related trends including MgH2 modification, the advancement of lightweight alloys and the use of machine learning. © 2025 The Authors
dc.identifier.doi10.1016/j.jpowsour.2025.238011
dc.identifier.instnameinstname:Universidad de Medellínspa
dc.identifier.issn3787753
dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellínspa
dc.identifier.repourlrepourl:https://repository.udem.edu.co/
dc.identifier.urihttps://hdl.handle.net/11407/9057
dc.language.isoeng
dc.publisher.facultyFacultad de Ingenieríasspa
dc.publisher.programIngeniería en Energíaspa
dc.publisher.programIngeniería de Materialesspa
dc.relation.citationvolume656
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-105012283074&doi=10.1016%2fj.jpowsour.2025.238011&partnerID=40&md5=99b320453bc4de29289a8e2986d11460
dc.relation.referencesSchlapbach L., Zuttel A., Hydrogen-Storage Materials for Mobile Applications, (2001)
dc.relation.referencesUS-DOE - hydrogen storage
dc.relation.referencesKumar A., Mukhopadhyay N.K., Yadav T.P., Chapter 3.2 - hydrogen storage in high entropy alloys, Towards Hydrogen Infrastructure, pp. 133-164, (2024)
dc.relation.referencesEdwards P.P., Kuznetsov V.L., David W.I.F., Hydrogen energy, Philos. Trans. R. Soc. A Math. Phys. Eng. Sci., 365, 1853, pp. 1043-1056, (2007)
dc.relation.referencesBishnoi A., Pati S., Sharma P., Architectural Design of Metal Hydrides to Improve the Hydrogen Storage Characteristics, (2024)
dc.relation.referencesWan H., Et al., Enhancing hydrogen storage properties of MgH2 using FeCoNiCrMn high entropy alloy catalysts, J. Mater. Sci. Technol., 149, pp. 88-98, (2023)
dc.relation.referencesMa X., Ding X., Chen R., Gao X., Su Y., Cui H., Enhanced hydrogen storage properties of ZrTiVAl1−xFex high-entropy alloys by modifying the Fe content, RSC Adv., 12, 18, pp. 11272-11281, (2022)
dc.relation.referencesLi S., Et al., Enhanced hydrogen storage performance of magnesium hydride catalyzed by medium-entropy alloy CrCoNi nanosheets, Int. J. Hydrogen Energy, (2023)
dc.relation.referencesOcampo R.A., Et al., Microwave-assisted synthesis of MgH2 nanoparticles for hydrogen storage applications, J. Nanoparticle Res., 27, 2, (2025)
dc.relation.referencesCortinez J.S., Et al., Production of Mg thin flakes with enhanced hydrogen storage performance, Int. J. Hydrogen Energy, 71, pp. 1191-1200, (2024)
dc.relation.referencesKeith A., Zlotea C., Szilagyi P.A., Perspective of interstitial hydrides of high-entropy alloys for vehicular hydrogen storage, Int. J. Hydrogen Energy, 52, pp. 531-546, (2024)
dc.relation.referencesHajkova P., Hornik J., Cizmarova E., Kalianko F., Metallic Materials for Hydrogen storage—A Brief Overview, (2022)
dc.relation.referencesYang F., Et al., Recent Progress on the Development of High Entropy Alloys (HEAs) for Solid Hydrogen Storage: a Review, (2022)
dc.relation.referencesLin H.J., Lu Y.S., Zhang L.T., Liu H.Z., Edalati K., Revesz A., Recent Advances in Metastable Alloys for Hydrogen Storage: a Review, (2022)
dc.relation.referencesAmiri A., Shahbazian-Yassar R., Recent Progress of high-entropy Materials for Energy Storage and Conversion, (2021)
dc.relation.referencesCheng Q.Y., Et al., High-Entropy Alloys for Accessing Hydrogen Economy via Sustainable Production of Fuels and Direct Application in Fuel Cells, (2023)
dc.relation.referencesLiu G., Et al., High-entropy Ti-Zr-Hf-Ni-Cu alloys as solid-solid phase change materials for high-temperature thermal energy storage, Intermetallics (Barking), 166, (2024)
dc.relation.referencesGiemza A., Sozanska M., Bala H., Modification of hydrogenation and corrosion properties of hydrogen storage material by amorphous TiCrFeCoNi HEA layer, Materials, 15, 7, (2022)
dc.relation.referencesZhang Z., Et al., Recent Research Progress on high-entropy Alloys as Electrocatalytic Materials, (2022)
dc.relation.referencesWang Z., Zhang C., Zhang Y., Hu J., Ultrasound-assisted synthesis of high-entropy materials for enhanced oxygen evolution electrocatalysis, Metals (Basel), 14, 4, (2024)
dc.relation.referencesLong L., Et al., High-entropy alloys for solid hydrogen storage, Hydrogen Energy, pp. 406-430, (2023)
dc.relation.referencesSomo T.R., Lototskyy M.V., Yartys V.A., Davids M.W., Nyamsi S.N., Hydrogen Storage Behaviours of High Entropy Alloys: a Review, (2023)
dc.relation.referencesQureshi T., Khan M.M., Pali H.S., The future of hydrogen economy: role of high entropy alloys in hydrogen storage, J. Alloys Compd., (2024)
dc.relation.referencesTingzhi S.I., Xiangxiang Z., Yongtao L.I., Dong-Myoung R., Qing'An Z., High-entropy alloy in-situ catalyzed Mg-based composite hydrogen storage material and preparation method thereof, (2022)
dc.relation.referencesTingzhi S.I., Xiangxiang Z., Yongtao L.I., Dong-Myoung R., Qing'An Z., Mg-containing room-temperature reversible hydrogen storage high-entropy alloy powder material and preparation method thereof, (2022)
dc.relation.referencesYunfei X.U.E., Xiaoxi L.I., Yunkai L.I., Benpeng W., Reversible room-temperature hydrogen storage high-entropy alloy and preparation and application thereof, (2021)
dc.relation.referencesJianguang Y., Ying W.U., Shaoxiong Z., Hydrogen storage high-entropy alloy and preparation method thereof, (2022)
dc.relation.referencesYuan W.U., Et al., Hydrogen storage high-entropy alloy taking body-centered cubic structure as principal thing and preparation method for hydrogen storage high-entropy alloy, (2017)
dc.relation.referencesMohammadi A., Et al., High-entropy hydrides for fast and reversible hydrogen storage at room temperature: binding-energy engineering via first-principles calculations and experiments, Acta Mater., 236, (2022)
dc.relation.referencesZhu Y., Et al., Development of AB2-type TiZrCrMnFeCoV intermetallic high-entropy alloy for reversible room-temperature hydrogen storage, J. Energy Storage, 75, (2024)
dc.relation.referencesLi L., Et al., Nanoscale microstructures and hydrogenation properties of an as-cast vanadium-based medium-entropy alloy, Int. J. Hydrogen Energy, 48, 75, pp. 29230-29239, (2023)
dc.relation.referencesShahi R.R., Gupta A.K., Kumari P., Perspectives of high entropy alloys as hydrogen storage materials, Int. J. Hydrogen Energy, (2022)
dc.relation.referencesYadav T.P., Kumar A., Verma S.K., Mukhopadhyay N.K., High-Entropy alloys for solid hydrogen storage: potentials and prospects, Trans. Indian National Academy Eng., 7, 1, pp. 147-156, (2022)
dc.relation.referencesMishra S.S., Mukhopadhyay S., Yadav T.P., Mukhopadhyay N.K., Srivastava O.N., Synthesis and characterization of hexanary Ti—Zr—V–Cr—Ni—Fe high-entropy Laves phase, J. Mater. Res., 34, 5, pp. 807-818, (2019)
dc.relation.referencesWang R., Et al., Effect of lattice distortion on the diffusion behavior of high-entropy alloys, J. Alloys Compd., 825, (2020)
dc.relation.referencesAidhy D.S., Chemical Randomness, Lattice Distortion and the Wide Distributions in the Atomic Level Properties in High Entropy Alloys, (2024)
dc.relation.referencesKim G., Et al., First-principles and machine learning predictions of elasticity in severely lattice-distorted high-entropy alloys with experimental validation, Acta Mater., 181, pp. 124-138, (2019)
dc.relation.referencesDematteis E.M., Berti N., Cuevas F., Latroche M., Baricco M., Substitutional Effects in TiFe for Hydrogen Storage: a Comprehensive Review, (2021)
dc.relation.referencesKong L., Cheng B., Wan D., Xue Y., A Review on BCC-Structured high-entropy Alloys for Hydrogen Storage, (2023)
dc.relation.referencesMartinez-Garcia A., Et al., Design and mechanosynthesis of low-weight high-entropy alloys with hydrogen storage potential properties, Int. J. Hydrogen Energy, 50, pp. 670-684, (2024)
dc.relation.referencesZhu X.-H., Zhang Y., Functional applications and data-driven design of high-entropy ceramics, High Entropy Alloys Mater., 2, 2, pp. 219-245, (2024)
dc.relation.referencesDas S., Robi P.S., Processing and characterizations of powder of the AlCoCuFeNi high entropy alloy, Emergent Mater., 6, 3, pp. 987-997, (2023)
dc.relation.referencesSerrano L., Et al., Development of Ti-V-Nb-Cr-Mn high entropy alloys for hydrogen storage, J. Alloys Compd., 945, (2023)
dc.relation.referencesCheng B., Et al., Solid-state hydrogen storage properties of ti–v–nb–cr high-entropy alloys and the associated effects of transitional metals (M = Mn, Fe, Ni), Acta Metall. Sin., (2022)
dc.relation.referencesSilva B.H., Zlotea C., Champion Y., Botta W.J., Zepon G., Design of TiVNb-(Cr, Ni or Co) multicomponent alloys with the same valence electron concentration for hydrogen storage, J. Alloys Compd., 865, (2021)
dc.relation.referencesLiu J., Et al., Microstructure and hydrogen storage properties of Ti–V–Cr based BCC-type high entropy alloys, Int. J. Hydrogen Energy, 46, 56, pp. 28709-28718, (2021)
dc.relation.referencesWu S., Chen Y., Kang W., Cai X., Zhou L., Hydrogen storage properties of MgTiVZrNb high-entropy alloy and its catalytic effect upon hydrogen storage in Mg, Int. J. Hydrogen Energy, 50, pp. 1113-1128, (2024)
dc.relation.referencesStrozi R.B., Leiva D.R., Huot J., Botta W.J., Zepon G., Synthesis and hydrogen storage behavior of Mg–V–Al–Cr–Ni high entropy alloys, Int. J. Hydrogen Energy, 46, 2, pp. 2351-2361, (2021)
dc.relation.referencesFloriano R., Et al., Hydrogen storage in TiZrNbFeNi high entropy alloys, designed by thermodynamic calculations, Int. J. Hydrogen Energy, 45, 58, pp. 33759-33770, (2020)
dc.relation.referencesPonsoni J.B., Aranda V., Nascimento T.D.S., Strozi R.B., Botta W.J., Zepon G., Design of multicomponent alloys with C14 laves phase structure for hydrogen storage assisted by computational thermodynamic, Acta Mater., 240, (2022)
dc.relation.referencesZhong Y., Otis R., McCormack S., Xiong W., Liu Z.K., Summary report of CALPHAD GLOBAL, 2021, Calphad: Computer Coupling of Phase Diagrams and Thermochemistry, (2023)
dc.relation.referencesGambaro S., Fenocchio L., Valenza F., Riani P., Cacciamani G., Combined experimental and CALPHAD investigation of equimolar AlCoCrFeNiX (X=Mo,Ta,W) high-entropy alloys, Calphad, 85, (2024)
dc.relation.referencesCheng B., Kong L., Li Y., Wan D., Xue Y., Hydrogen desorption kinetics of V30Nb10(TixCr1–x)60 high-entropy alloys, Metals (Basel), 13, 2, (2023)
dc.relation.referencesEnblom V., Et al., A combined experimental and machine learning exploration of Ti2-xZrxMnCrFeNi high entropy laves hydrides, Materialia, 40, (2025)
dc.relation.referencesLi C., Et al., Improvement of hydrogen absorption and desorption properties of TiFe-based alloys by adding yttrium, J. Alloys Compd., 927, (2022)
dc.relation.referencesKunce I., Polanski M., Czujko T., Microstructures and hydrogen storage properties of LaNiFeVMn alloys, Int. J. Hydrogen Energy, 42, 44, pp. 27154-27164, (2017)
dc.relation.referencesBasem A., Et al., Characterization of FeCoNiCr high-entropy alloys manufactured by powder metallurgy technique, J. Mater. Res. Technol., 30, pp. 88-100, (2024)
dc.relation.referencesPradhan P., Shadangi Y., Shivam V., Mukhopadhyay N.K., Powder metallurgical processing of CrMnFeCoMo high entropy alloy: phase evolution, microstructure, thermal stability and mechanical properties, J. Alloys Compd., 935, (2023)
dc.relation.referencesPark K.B., Et al., Spark plasma sintering behavior of TaNbHfZrTi high-entropy alloy powder synthesized by hydrogenation-dehydrogenation reaction, Intermetallics (Barking), 130, (2021)
dc.relation.referencesTorralba J.M., Alvaredo P., Garcia-Junceda A., High-Entropy Alloys Fabricated via Powder Metallurgy. A Critical Review, (2019)
dc.relation.referencesXing Q.-W., Zhang Y., Xing Q., High entropy alloys-manufacturing routes, Metals Alloys, (2020)
dc.relation.referencesDavids M.W., Et al., Effect of preparation routes on the performance of a multi-component AB2-type hydrogen storage alloy, JPhys Energy, 6, 3, (2024)
dc.relation.referencesKumar A., Abu Shaz M., Mukhopadhyay N.K., Yadav T.P., Phase transformation of AB5 to AB2 type phase on substitution of Mn with Zr in TiVCoNi (ZrxMn2-x) (x = 0, 0.3, 0.6, 1.0) high entropy alloys, Mater. Chem. Phys., 318, (2024)
dc.relation.referencesSuryanarayana C., Mechanical alloying and milling, Prog. Mater. Sci., 46, 1-2, pp. 1-184, (2001)
dc.relation.referencesEdalati K., Et al., Impact of severe plastic deformation on kinetics and thermodynamics of hydrogen storage in magnesium and its alloys, Chinese Soc. Metals, (2023)
dc.relation.referencesLuo L., Et al., Nanoscale microstructures and novel hydrogen storage performance of as cast V47Fe11Ti30Cr10RE2 (RE = La, Ce, Y, Sc) medium entropy alloys, J. Alloys Compd., 913, (2022)
dc.relation.referencesZhao H., Yao P., Zhao Y., Zeng Z., Xia C., Yang T., Microstructure and hydrogen storage properties of Zr-based AB2-type high entropy alloys, J. Alloys Compd., 960, (2023)
dc.relation.referencesWu S., Li W., Liu X., Wang Y., Cai X., Zhou L., Evolution of the phase and hydrogen storage properties of new-type VTiCrFeMn high-entropy alloy prepared via mechanical alloying, Integrated Ferroelectrics Int. J., 235, 1, pp. 17-28, (2023)
dc.relation.referencesCardoso K.R., Roche V., Antiqueira F., Zepon G., Champion Y., Hydrogen storage in MgAlTiFeNi high entropy alloy, J. Alloys Compounds, 858, (2021)
dc.relation.referencesZepon G., Et al., Hydrogen-induced phase transition of MgZrTiFe0.5Co0.5Ni0.5 high entropy alloy, Int. J. Hydrogen Energy, 43, 3, pp. 1702-1708, (2018)
dc.relation.referencesStrozi R.B., Leiva D.R., Huot J., Botta W.J., Zepon G., An approach to design single BCC Mg-containing high entropy alloys for hydrogen storage applications, Int. J. Hydrogen Energy, 46, 50, pp. 25555-25561, (2021)
dc.relation.referencesLiu X., Wu S., Cai X., Zhou L., Hydrogen storage behaviour of Cr- and Mn-doped Mg2Ni alloys fabricated via high-energy ball milling, Int. J. Hydrogen Energy, 48, 45, pp. 17202-17215, (2023)
dc.relation.referencesCermak J., Kral L., Roupcova P., A new light-element multi-principal-elements alloy AlMg2TiZn and its potential for hydrogen storage, Renew. Energy, 198, pp. 1186-1192, (2022)
dc.relation.referencesPanigrahi A., Et al., Microstructure and mechanical properties of novel tungsten heavy alloys prepared using FeNiCoCrCu HEA as binder, Mater. Sci. Eng., A, 832, (2022)
dc.relation.referencesSahlberg M., Karlsson D., Zlotea C., Jansson U., Superior hydrogen storage in high entropy alloys, Sci. Rep., 6, (2016)
dc.relation.referencesAranda V., Leiva D.R., Huot J., Botta W.J., Zepon G., Hydrogen storage properties of the TiVFeZr multicomponent alloy with C14-type laves phase structure, Intermetallics (Barking), 162, (2023)
dc.relation.referencesKumar A., Yadav T., Shaz M., Mukhopadhyay N.K., Hydrogen storage properties in rapidly solidified TiZrVCrNi high‐entropy alloys, Energy Storage, 6, (2023)
dc.relation.referencesLiang J., Et al., The synergistic effect of Ni and C14 Laves phase on the hydrogen storage properties of TiVZrNbNi high entropy hydrogen storage alloy, Intermetallics (Barking), 164, (2024)
dc.relation.referencesKumar A., Yadav T.P., Shaz M.A., Mukhopadhyay N.K., Hydrogen storage performance of C14 type Ti0.24V0.17Zr0.17Mn0.17Co0.17Fe0.08 high entropy intermetallics, Trans. Indian National Academy Eng., (2023)
dc.relation.referencesKalantari H., Khayati G.R., Adeli M., Structure investigation of AlFeNiTiZn nanocrystalline high entropy alloy, Vacuum, 210, (2023)
dc.relation.referencesPineda Romero N., Et al., Large destabilization of (TiVNb)-Based hydrides via (Al, Mo) addition: insights from experiments and data-driven models, ACS Appl. Energy Mater., 6, 24, pp. 12560-12572, (2023)
dc.relation.referencesLiu H., Zhang J., Sun P., Zhou C., Liu Y., Fang Z.Z., An Overview of TiFe Alloys for Hydrogen Storage: Structure, Processes, Properties, and Applications, (2023)
dc.relation.referencesPasquini L., Et al., Magnesium- and Intermetallic Alloys-based Hydrides for Energy Storage: Modelling, Synthesis and Properties, (2022)
dc.relation.referencesBouzidi A., Laversenne L., Nassif V., Elkaim E., Zlotea C., Hydrogen storage properties of a new Ti-V-Cr-Zr-Nb high entropy alloy, Hydrogen, 3, 2, pp. 270-284, (2022)
dc.relation.referencesLiu J., Et al., Hydrogen storage properties of V0.3Ti0.3Cr0.25Mn0.1Nb0.05 high entropy alloy, Int. J. Hydrogen Energy, 47, 61, pp. 25724-25732, (2022)
dc.relation.referencesKumar A., Yadav T.P., Mukhopadhyay N.K., Notable hydrogen storage in Ti–Zr–V–Cr–Ni high entropy alloy, Int. J. Hydrogen Energy, 47, 54, pp. 22893-22900, (2022)
dc.relation.referencesKao Y.F., Et al., Hydrogen storage properties of multi-principal-component CoFeMnTi xVyZrz alloys, Int. J. Hydrogen Energy, 35, 17, pp. 9046-9059, (2010)
dc.relation.referencesBouzidi A., Et al., Exploring the hydrogen sorption capabilities of a novel Ti-V-Mn-Zr-Nb high-entropy alloy, Inorganics (Basel), 11, 5, (2023)
dc.relation.referencesPark K.B., Et al., Characterizations of hydrogen absorption and surface properties of Ti0.2Zr0.2Nb0.2V0.2Cr0.17Fe0.03 high entropy alloy with dual phases, Met. Mater. Int., 28, 2, pp. 565-571, (2022)
dc.relation.referencesZlotea C., Bouzidi A., Montero J., Ek G., Sahlberg M., Compositional effects on the hydrogen storage properties in a series of refractory high entropy alloys, Front. Energy Res., 10, (2022)
dc.relation.referencesHidalgo-Jimenez J., Cubero-Sesin J.M., Edalati K., Khajavi S., Huot J., Effect of high-pressure torsion on first hydrogenation of Laves phase Ti0.5Zr0.5(Mn1-xFex)Cr1 (x = 0, 0.2 and 0.4) high entropy alloys, J. Alloys Compd., 969, (2023)
dc.relation.referencesFukagawa T., Saito Y., Matsuyama A., Effect of varying Ni content on hydrogen absorption–desorption and electrochemical properties of Zr-Ti-Ni-Cr-Mn high-entropy alloys, J. Alloys Compd., 896, (2022)
dc.relation.referencesMa X., Ding X., Chen R., Cao W., Song Q., Study on hydrogen storage property of (ZrTiVFe)xAly high-entropy alloys by modifying Al content, Int. J. Hydrogen Energy, 47, 13, pp. 8409-8418, (2022)
dc.relation.referencesShen H., Et al., Compositional dependence of hydrogenation performance of Ti-Zr-Hf-Mo-Nb high-entropy alloys for hydrogen/tritium storage, J. Mater. Sci. Technol., 55, pp. 116-125, (2020)
dc.relation.referencesGong J., Li Y., Song X., Wang Y., Chen Z., Hydrogen storage of high entropy alloy NbTiVZr and its effect on mechanical properties: a first-principles study, Vacuum, 219, (2024)
dc.relation.referencesStrozi R.B., Et al., High entropy alloys containing immiscible Mg and refractory elements: synthesis, structure, and hydrogen storage properties, J. Alloys Compd., 969, (2023)
dc.relation.referencesLiang J., Et al., Formation of Zr-rich BCC phase and its relation on the hydrogen storage properties of TiVNbZr high entropy alloy, Int. J. Hydrogen Energy, 48, 86, pp. 33610-33619, (2023)
dc.relation.referencesHu J., Et al., A density functional theory study of the hydrogen absorption in high entropy alloy TiZrHfMoNb, Inorg. Chem., 59, 14, pp. 9774-9782, (2020)
dc.relation.referencesMontero J., Ek G., Sahlberg M., Zlotea C., Improving the hydrogen cycling properties by Mg addition in Ti-V-Zr-Nb refractory high entropy alloy, Scr. Mater., 194, (2021)
dc.relation.referencesFerraz M.D.B., Botta W.J., Zepon G., Synthesis, characterization and first hydrogen absorption/desorption of the Mg35Al15Ti25V10Zn15 high entropy alloy, Int. J. Hydrogen Energy, 47, 54, pp. 22881-22892, (2022)
dc.relation.referencesAndrade G., Silva B.H., Zepon G., Floriano R., Hydrogen storage properties of Zr-based multicomponent alloys with C14-Laves phase structure derived from the Zr–Cr–Mn–Fe–Ni system, Int. J. Hydrogen Energy, 51, pp. 246-254, (2024)
dc.relation.referencesWei M., Liu Y., Xing X., Zhang Z., Liu T., (TiVZrNb)83Cr17 high-entropy alloy as catalyst for hydrogen storage in MgH2, Chem. Eng. J., 476, (2023)
dc.relation.referencesMa X., Ding X., Chen R., Chen X., Song Q., Cui H., Study on microstructure and the hydrogen storage behavior of a TiVZrNbFe high-entropy alloy, Intermetallics (Barking), 157, (2023)
dc.relation.referencesMa X., Ding X., Chen R., Zhang J., Song Q., Cui H., Microstructural features and improved reversible hydrogen storage properties of ZrTiVFe high-entropy alloy via Cu alloying, Int. J. Hydrogen Energy, 48, 7, pp. 2718-2730, (2023)
dc.relation.referencesKunce I., Polanski M., Bystrzycki J., Microstructure and hydrogen storage properties of a TiZrNbMoV high entropy alloy synthesized using Laser Engineered Net Shaping (LENS), Int. J. Hydrogen Energy, 39, 18, pp. 9904-9910, (2014)
dc.relation.referencesKunce I., Polanski M., Czujko T., Microstructures and hydrogen storage properties of La–Ni–Fe–V–Mn alloys, Int. J. Hydrogen Energy, 42, 44, pp. 27154-27164, (2017)
dc.relation.referencesChen J., Et al., Superior cycle life of TiZrFeMnCrV high entropy alloy for hydrogen storage, Scr. Mater., 212, (2022)
dc.relation.referencesAndrade G., Et al., Crystal structure and hydrogen storage properties of AB-type TiZrNbCrFeNi high-entropy alloy, Int. J. Hydrogen Energy, (2023)
dc.relation.referencesEdalati P., Et al., Reversible room temperature hydrogen storage in high-entropy alloy TiZrCrMnFeNi, Scr. Mater., 178, pp. 387-390, (2020)
dc.relation.referencesChen J., Et al., Enhancement of vanadium addition on hydrogen storage properties of high entropy alloys TiZrFeMnCrVx, Int. J. Hydrogen Energy, 50, pp. 1223-1233, (2024)
dc.relation.referencesKomeili M., Arabi H., Pourarian F., Structural investigation and hydrogenation properties of TiZrXMnFeNi (X = Cr, Mo, and W) high entropy alloys, J. Alloys Compd., 967, (2023)
dc.relation.referencesKunce I., Polanski M., Bystrzycki J., Structure and hydrogen storage properties of a high entropy ZrTiVCrFeNi alloy synthesized using Laser Engineered Net Shaping (LENS), Int. J. Hydrogen Energy, 38, 27, pp. 12180-12189, (2013)
dc.relation.referencesDangwal S., Edalati K., High-entropy alloy TiV2ZrCrMnFeNi for hydrogen storage at room temperature with full reversibility and good activation, Scr. Mater., 238, (2024)
dc.relation.referencesDangwal S., Edalati K., Significance of interphase boundaries on activation of high-entropy alloys for room-temperature hydrogen storage, Int. J. Hydrogen Energy, 50, pp. 626-636, (2024)
dc.relation.referencesVarcholova D., Et al., New-generation materials for hydrogen storage in medium-entropy alloys, Materials, 17, 12, (2024)
dc.relation.referencesTakeuchi A., Inoue A., Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element, Mater. Trans., 46, 12, pp. 2817-2829, (2005)
dc.relation.referencesMishra S.S., Yadav T.P., Srivastava O.N., Mukhopadhyay N.K., Biswas K., Formation and stability of C14 type Laves phase in multi component high-entropy alloys, J. Alloys Compd., 832, (2020)
dc.relation.referencesShashikala K., Hydrogen storage materials, Functional Materials, pp. 607-637, (2012)
dc.relation.referencesCermak J., Kral L., Roupcova P., Hydrogen storage in TiVCrMo and TiZrNbHf multiprinciple-element alloys and their catalytic effect upon hydrogen storage in Mg, Renew. Energy, 188, pp. 411-424, (2022)
dc.relation.referencesLi P., Et al., Electronic structure regulation toward the improvement of the hydrogenation properties of TiZrHfMoNb high-entropy alloy, J. Alloys Compd., 905, (2022)
dc.relation.referencesZhong T., Et al., FeCoNiCrMo high entropy alloy nanosheets catalyzed magnesium hydride for solid-state hydrogen storage, Int. J. Miner. Metall. Mater., 30, 11, pp. 2270-2279, (2023)
dc.relation.referencesLiu J., Hou J., An F., Qian B., Liebscher C.H., Lu W., Characterization of compositionally complex hydrides in a metastable refractory high-entropy alloy, Acta Metall. Sin., 36, 7, pp. 1173-1178, (2023)
dc.relation.referencesDeng Y., Et al., Hydrogen storage properties of Mg0.10Ti0.30V0.25Zr0.10Nb0.25 lightweight high entropy alloy: a theoretical study, Int. J. Hydrogen Energy, 50, pp. 314-323, (2024)
dc.relation.referencesYadav Y.K., Shaz M.A., Yadav T.P., Al–Cu–Fe–Ni–Ti high entropy alloy nanoparticles as new catalyst for hydrogen sorption in MgH2, Int. J. Hydrogen Energy, (2024)
dc.relation.referencesVerma S.K., Mishra S.S., Mukhopadhyay N.K., Yadav T.P., Superior catalytic action of high-entropy alloy on hydrogen sorption properties of MgH2, Int. J. Hydrogen Energy, 50, pp. 749-762, (2024)
dc.relation.referencesWang L., Et al., Surprising cocktail effect in high entropy alloys on catalyzing magnesium hydride for solid-state hydrogen storage, Chem. Eng. J., 465, (2023)
dc.relation.referencesZhou Z., Zhou Y., He Q., Ding Z., Li F., Yang Y., Machine learning guided appraisal and exploration of phase design for high entropy alloys, npj Comput. Mater., 5, 1, (2019)
dc.relation.referencesSingh S., Katiyar N.K., Goel S., Joshi S.N., Phase prediction and experimental realisation of a new high entropy alloy using machine learning, Sci. Rep., 13, 1, (2023)
dc.relation.referencesDangwal S., Ikeda Y., Grabowski B., Edalati K., Machine learning to explore high-entropy alloys with desired enthalpy for room-temperature hydrogen storage: prediction of density functional theory and experimental data, Chem. Eng. J., 493, (2024)
dc.rights.accesoRestricted access
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.sourceJournal of Power Sources
dc.sourceJ Power Sources
dc.sourceScopus
dc.subjectHigh entropy alloy
dc.subjectHydrogen storage
dc.subjectMetal hydride
dc.subjectSolid solution
dc.subjectThermodynamics
dc.subjectEntropy
dc.subjectHigh-entropy alloys
dc.subjectHydrides
dc.subjectHydrogen storage alloys
dc.subjectMagnesium compounds
dc.subjectPatents and inventions
dc.subjectSolid solutions
dc.subjectAcademic paper
dc.subjectFuture trends
dc.subjectGoogle scholar
dc.subjectHigh entropy alloys
dc.subjectMetal-hydrides
dc.subjectRecent progress
dc.subjectRecent trends
dc.subjectSolid hydrogen
dc.subjectSolid-state hydrogen storage
dc.subjectSystematic Review
dc.subjectHydrogen storage
dc.titleChallenges and potential future trends on high entropy alloy for solid hydrogen storage: Systematic review
dc.typeReview
dc.type.localRevisiónspa
dc.type.versioninfo:eu-repo/semantics/publishedVersion

Archivos

Colecciones