Production of Mg thin flakes with enhanced hydrogen storage performance

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dc.contributor.affiliationCortinez, J.S., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationGómez, A., Grupo Catalizadores y Adsorbentes – CATALAD, Instituto de Química, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationZuleta Gil, A.A., Grupo de Investigación de Estudios en Diseño - GED, Facultad de Diseño Industrial, Universidad Pontificia Bolivariana, Sede Medellín, Circular 1 No 70 – 01, Medellín, Colombia
dc.contributor.affiliationTamayo, J.A., Grupo Calidad Metrología y Producción, Instituto Tecnológico Metropolitano ITM, Antioquia, Medellín, 050034, Colombia
dc.contributor.affiliationCorrea, E., Grupo de Investigación Materiales con Impacto – MAT&MPAC, Facultad de Ingenierías, Universidad de Medellín UdeM, Carrera 87 No 30 – 65, Medellín, Colombia
dc.contributor.affiliationBolívar, F.J., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationEcheverria, F.E., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.authorCortinez J.S
dc.contributor.authorGómez A
dc.contributor.authorZuleta Gil A.A
dc.contributor.authorTamayo J.A
dc.contributor.authorCorrea E
dc.contributor.authorBolívar F.J
dc.contributor.authorEcheverria F.E.
dc.date.accessioned2024-07-31T21:07:03Z
dc.date.available2024-07-31T21:07:03Z
dc.date.issued2024
dc.descriptionFlake-like particles are interesting materials for the preparation of alloys and homogeneous nanocomposites, they also have potential use as hydrogen storage materials. However, limited information is available regarding the synthesis of pure magnesium with flake-like morphology. In this study, the successful production of Mg flakes was conducted using a cost-effective and simple method, such as high energy ball milling. Various milling parameters, including different milling times and process control agents, were tested. Optimal conditions led to the formation of coarse flakes with ∼1.72 μm thickness, while a two-step milling process produced thinner flakes with submicron thickness (∼242 nm). Ductilization of the material and a significant reduction in crystal size during the milling process were observed via X-ray diffraction. Isothermal kinetic tests at 350 °C and 20 bar revealed improved hydrogen storage performance for both coarse and thin flakes compared to pristine Mg. Coarse flakes achieved capacities of 4.1 wt% in 60 min while thin flakes reached 4.6 wt% in 6 min, compared to 3.4 wt% achieved in 100 min by pristine Mg. The improved behavior of thin flake-shaped Mg was maintained at 300 °C and 20 bar, with 4.5 wt% of hydrogen absorbed in 6 min. Even at lower testing pressures (10 bar) higher capacities were achieved at the expense of slower kinetics. These findings suggest that thin flake-shaped Mg is a suitable material with enhanced performance for hydrogen storage applications. © 2024 The Authors
dc.identifier.doi10.1016/j.ijhydene.2024.05.254
dc.identifier.instnameinstname:Universidad de Medellínspa
dc.identifier.issn3603199
dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellínspa
dc.identifier.repourlrepourl:https://repository.udem.edu.co/
dc.identifier.urihttp://hdl.handle.net/11407/8462
dc.language.isoeng
dc.publisherElsevier Ltdspa
dc.publisher.facultyFacultad de Ingenieríasspa
dc.relation.citationendpage1200
dc.relation.citationstartpage1191
dc.relation.citationvolume71
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85193966001&doi=10.1016%2fj.ijhydene.2024.05.254&partnerID=40&md5=944ed2efcb38c990f6e48e5a63cae5bc
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dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.sourceInternational Journal of Hydrogen Energy
dc.sourceInt J Hydrogen Energy
dc.sourceScopus
dc.subjectHigh energy ball millingeng
dc.subjectHydrogen storageeng
dc.subjectHydrogenation kineticseng
dc.subjectMagnesium flakeseng
dc.subjectNanostructureseng
dc.subjectBall millingeng
dc.subjectCost effectivenesseng
dc.subjectKineticseng
dc.subjectMagnesiumeng
dc.subjectMilling (machining)eng
dc.subjectCost-effective methodseng
dc.subjectFlake-like particleseng
dc.subjectHigh-energy ball millingeng
dc.subjectHydrogen storage materialseng
dc.subjectHydrogenation kineticseng
dc.subjectLimited informationeng
dc.subjectMagnesium flakeeng
dc.subjectMilling processeng
dc.subjectPure magnesiumeng
dc.subjectStorage performanceeng
dc.subjectHydrogen storageeng
dc.titleProduction of Mg thin flakes with enhanced hydrogen storage performanceeng
dc.typearticle
dc.type.localArtículospa
dc.type.versioninfo:eu-repo/semantics/publishedVersion

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