Catalytic effect of commercial carbon-coated nickel nanoparticles on the hydrogen storage performance of magnesium hydride

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dc.contributor.affiliationOcampo R.A., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationArias-Velandia J., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationLenis J.A., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationZuleta Gil A.A., Grupo de Investigación de Estudios en Diseño - GED, Facultad de Diseño Industrial, Universidad Pontificia Bolivariana, Sede Medellín, Circular 1 No 70 – 01, Medellín, Colombia
dc.contributor.affiliationBello S., Grupo de Investigación Materiales con Impacto – MAT&MPAC, Facultad de Ingenierías, Universidad de Medellín UdeM, Carrera 87 No 30 – 65, Medellín, Colombia
dc.contributor.affiliationCorrea E., Grupo de Investigación Materiales con Impacto – MAT&MPAC, Facultad de Ingenierías, Universidad de Medellín UdeM, Carrera 87 No 30 – 65, Medellín, Colombia
dc.contributor.affiliationArrieta C., Grupo de Investigación en Ingeniería en Energía – GRINEN, Facultad de Ingenierías, Universidad de Medellín UdeM, Carrera 87 No 30 – 65, Medellín, Colombia
dc.contributor.affiliationBolívar F.J., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.affiliationEcheverría F.E., Centro de Investigación, Innovación y Desarrollo de Materiales – CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No 52 – 21, Medellín, Colombia
dc.contributor.authorOcampo R.A.
dc.contributor.authorArias-Velandia J.
dc.contributor.authorLenis J.A.
dc.contributor.authorZuleta Gil A.A.
dc.contributor.authorBello S.
dc.contributor.authorCorrea E.
dc.contributor.authorArrieta C.
dc.contributor.authorBolívar F.J.
dc.contributor.authorEcheverría F.E.
dc.date.accessioned2025-09-08T14:23:49Z
dc.date.available2025-09-08T14:23:49Z
dc.date.issued2025
dc.descriptionMagnesium is an excellent option for hydrogen storage due to its substantial capacity, estimated at approximately 7.6 wt %. However, the desorption temperature usually exceeds 350 °C because of slow kinetics and significant thermodynamic stability. Nickel has been used as a catalyst to enhance the kinetics of MgH2 hydrogen desorption and absorption, as well as to reduce the dehydrogenation temperature. Commercial carbon-coated nickel nanoparticles were employed to catalyze hydrogen desorption and absorption in MgH2. These nanoparticles were incorporated into the MgH2 through two methods: before and after the ball milling process. Using carbon-coated nickel nanoparticles decreases the onset temperature of dehydrogenation from 321 °C in as-milled MgH2 to below 255 °C for both sample types containing carbon-coated nickel nanoparticles. The activation energy falls from 152 kJ/mol in as-milled MgH2 to at least 107 kJ/mol, with a minimum value of 81 kJ/mol. During dehydrogenation at 300 °C, the best samples evaluated take 10 min to reach 6.38 wt % and 40 min to achieve 5 wt % at 275 °C. Furthermore, MgH2 with commercial carbon-coated nickel nanoparticles absorbs 4.5 wt % of hydrogen in 60 min at 150 °C and has a retention capacity in hydrogen desorption of 92 % after 10 cycles. Our results suggest carbon-coated nickel nanoparticles can be added to MgH2 without ball milling to catalyze hydrogen desorption and absorption. This type of catalysis may be appealing for nanosized magnesium-based materials, where ball milling can agglomerate particles or alter a specific morphology. © 2025 The Authors
dc.identifier.doi10.1016/j.ijhydene.2025.04.226
dc.identifier.instnameinstname:Universidad de Medellínspa
dc.identifier.issn3603199
dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellínspa
dc.identifier.repourlrepourl:https://repository.udem.edu.co/
dc.identifier.urihttp://hdl.handle.net/11407/9107
dc.language.isoeng
dc.publisher.facultyFacultad de Ingenieríasspa
dc.publisher.programIngeniería en Energíaspa
dc.relation.citationendpage100
dc.relation.citationstartpage91
dc.relation.citationvolume129
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-105003119909&doi=10.1016%2fj.ijhydene.2025.04.226&partnerID=40&md5=518cccd8f6e1625112d5d33ad3d8a145
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dc.rights.accesoRestricted access
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.sourceInternational Journal of Hydrogen Energy
dc.sourceInt J Hydrogen Energy
dc.sourceScopus
dc.subjectHydrogen storage
dc.subjectMagnesium hydride
dc.subjectNanoparticles
dc.subjectNickel
dc.subjectCatalysis
dc.subjectDehydrogenation
dc.subjectMetal nanoparticles
dc.subjectNanoclay
dc.subjectNickel coatings
dc.subjectCarbon coated nickel nanoparticle
dc.subjectCatalyse
dc.subjectCatalytic effects
dc.subjectDesorption temperatures
dc.subjectHydrogen absorption
dc.subjectHydrogen desorption
dc.subjectMagnesium hydride
dc.subjectStorage performance
dc.subjectSubstantial capacity
dc.subject]+ catalyst
dc.subjectActivation energy
dc.titleCatalytic effect of commercial carbon-coated nickel nanoparticles on the hydrogen storage performance of magnesium hydride
dc.typeArticle
dc.type.localArtículospa
dc.type.versioninfo:eu-repo/semantics/publishedVersion

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