Eco-friendly reuse of agricultural wastes to produce biocomposites with high potential in water treatment and fertilizers

dc.contributor.affiliationPérez, S., Grupo de Investigación Materiales Con Impacto (Mat & amp;Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia
dc.contributor.affiliationGiraldo, S., Grupo de Investigación Materiales Con Impacto (Mat & amp;Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia
dc.contributor.affiliationForgionny, A., Grupo de Investigación Materiales Con Impacto (Mat & amp;Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia
dc.contributor.affiliationFlórez, E., Grupo de Investigación Materiales Con Impacto (Mat & amp;Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia
dc.contributor.affiliationAcelas, N., Grupo de Investigación Materiales Con Impacto (Mat & amp;Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia
dc.contributor.authorPérez S
dc.contributor.authorGiraldo S
dc.contributor.authorForgionny A
dc.contributor.authorFlórez E
dc.contributor.authorAcelas N.
dc.date.accessioned2024-12-27T20:51:45Z
dc.date.available2024-12-27T20:51:45Z
dc.date.issued2024
dc.descriptionLarge quantities of orange peel wastes are generated and require adequate management and disposal into the environment. Agricultural waste valorization is a strong research topic, due to the increasing need for achieving a sustainable environment. Especially, the development of adsorbent materials applied to wastewater treatment for efficient phosphorus recovery and reuse systems is a challenge of current interest in research. In this work, a novel low-cost biocomposite was obtained by calcination of orange peel (OP) and eggshell (ES), which is highly effective for P recovery from synthetic aqueous solutions and domestic wastewater. After calcination at 700 °C, the material with a ratio by weight of OP/ES = 1 showed a high adsorption capacity (Qmax = 315.25 mg P/g) compared to other materials previously reported. The XRD and FTIR characterization results of the materials after the P removal showed that brushite (Ca(HPO4)•2H2O) is the main calcium phase obtained at pH 6, while apatite (Ca5(PO4)3OH) is favored at a pH higher than 8. Moreover, the ESOP adsorbents showed a high P adsorption from wastewater, with 98.6% of P recovery as apatite. Additionally, Ca5(PO4)3OH and Ca(HPO4)•2H2O phases exhibited a high solubility of P in 2% formic acid releasing up to 97.50 and 194.22 mg P/g. The results of this work indicate that calcined ESOP is a promising material for P recovery from aqueous solution, forming calcium phosphates with great potential to be used as alternative phosphate fertilizer, contributing to implementing the 3R slogan “Reduce, Reuse, Recycle” based on a circular economy. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022.
dc.identifier.doi10.1007/s13399-022-02948-6
dc.identifier.instnameinstname:Universidad de Medellínspa
dc.identifier.issn21906815
dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellínspa
dc.identifier.repourlrepourl:https://repository.udem.edu.co/
dc.identifier.urihttp://hdl.handle.net/11407/8686
dc.language.isoeng
dc.publisherSpringer Science and Business Media Deutschland GmbHspa
dc.publisher.facultyFacultad de Ciencias Básicasspa
dc.relation.citationendpage8547
dc.relation.citationissue7
dc.relation.citationstartpage8537
dc.relation.citationvolume14
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85132206624&doi=10.1007%2fs13399-022-02948-6&partnerID=40&md5=637e39576b77def6cf0364fea9e1ac20
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dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.sourceBiomass Conversion and Biorefinery
dc.sourceBiomass Convers. Biorefinery
dc.sourceScopus
dc.subjectAdsorptioneng
dc.subjectEggshelleng
dc.subjectFertilizereng
dc.subjectOrange peeleng
dc.subjectPhosphoruseng
dc.subjectAgricultural wasteseng
dc.subjectApatiteeng
dc.subjectCalcinationeng
dc.subjectCalcium phosphateeng
dc.subjectCitrus fruitseng
dc.subjectComposite materialseng
dc.subjectPhosphoruseng
dc.subjectWastewater disposaleng
dc.subjectWastewater reclamationeng
dc.subjectWastewater treatmenteng
dc.subjectWater conservationeng
dc.subjectBiocompositeeng
dc.subjectEco-friendlyeng
dc.subjectEggshelleng
dc.subjectHigh potentialeng
dc.subjectOrange peel wasteseng
dc.subjectOrange peelseng
dc.subjectResearch topicseng
dc.subjectReuseeng
dc.subjectSustainable environmenteng
dc.subjectWaste valorizationseng
dc.subjectAdsorptioneng
dc.titleEco-friendly reuse of agricultural wastes to produce biocomposites with high potential in water treatment and fertilizerseng
dc.typeArticle
dc.type.localArtículo de revistaspa
dc.type.versioninfo:eu-repo/semantics/publishedVersion

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